Which of the following sets of quantum numbers is not possible?

1.
Which of the following sets of quantum numbers is not possible?

1. n = 3, l = 2, m = 0, s = –1/22. n = 4, l = 4, m = +3, s = +1/23. n = 3, l = 1, m = –2, s = –1/24. n = 2, l = 0, m = 0, s = +1/2