van der Waals' constant a and b are related with ___ respectively.

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1.
van der Waals' constant a and b are related with ___ respectively.

1. Attractive force and bond energy of molecules2. Attaractive force and excluded volume of molecules3. Volume and repulsive force of molecules4. Shape and repulsive force of molecule

van der Waals' constant a and b are related with ___ respectively.